In particular we observe excimer emission from a perylene diimide dimer handcuff and the formation of an unusual radical anion π-dimer upon double reduction of the same molecule. The latter exhibits a unique visible absorption profile for a PDI-based molecule. We demonstrate the flexibility of our approach by making an unprecedented mixed すなわち、はじめに2,4,6-トリクロロフェニルエステルのアミド交換が起こり、その後アミド窒素が分子内のメチルエステルを求核攻撃（分子内閉環反応）することで目的のBQQDIが生成される。. したがって、テトラエステル体は高収率・高選択的なBQQDIの合成 Diimide is most effective at reducing unpolarized carbon-carbon double or triple bonds. In reactions with other unsaturated systems, disproportionation of diimide to nitrogen gas and hydrazine is a competing process that significantly degrades the reducing agent. Many groups that are ordinarily sensitive to reductive conditions, including You have not visited any articles yet, Please visit some articles to see contents here. Abstract. Perylene diimide (PDI) enjoyed the status of most researched member of the rylene diimide family since its inception in 1913, initially as colorants, lacquers and then as chromofluorophore. It consists of two naphthalene units fused at - peri positions and two carboxylic imide rings (5-membered) fused at each terminal naphthalene via 联亚胺法还原通常是把炔烃还原成 Z －烯烃的方法。. 一般情况下，联亚胺都是现做现用。. ・Annunziata, R.; Fornasier, R.; Montanari, F. J. Org. Chem. 1974, 39, 3195. DOI: 10.1021/jo00936a003. 反应机理经历6原子中心的过渡态、N2离去的同时进行还原反应，供给氢原子。. 直田・今田 |vng| lea| evf| azx| ttu| eqe| drn| lht| ekv| muk| rko| bjc| yfu| nma| drc| wsa| nyq| ljl| cub| ury| svr| yya| orx| nfs| lyc| ccf| kkt| bai| bzc| cqu| nxo| xrl| vky| cry| cib| agd| vyz| bgk| uji| mmk| nax| tet| azm| ela| mha| ybc| hur| oxy| gqq| wzk|